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If the equilibrium constant for a reaction is 1 × 10-5, this means that the equilibrium mixture contains mostly reactants.

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Carbon monoxide binds to hemoglobin 140 times more strongly than oxygen does. What does this tell you about the equilibrium constants for the two reactions of hemoglobin with carbon monoxide and oxygen?


A) The equilibrium constant for the binding of CO is greater.
B) The equilibrium constant for the binding of oxygen is greater.
C) The concentration of carbon monoxide at equilibrium is twice that of oxygen.
D) Oxygen and carbon monoxide have the same formula mass.
E) Oxygen and carbon monoxide react with hemoglobin in different fashions.

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In a catalyzed chemical reaction, one function of a catalyst is to


A) increase the number of successful reactant collisions.
B) decrease the concentration of reactants.
C) change the equilibrium concentrations of the products and reactants.
D) increase the energy given off during the reaction.
E) increase the temperature at which the reaction is carried out.

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A reaction that can proceed in either the forward or the reverse direction as written is called a ________ reaction.


A) reversible
B) miniscule
C) microscopic
D) solid phase
E) favored

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For the following reaction, the equilibrium constant Kc is 2.0 at a certain temperature. The reaction is endothermic. What do you expect to happen to the concentration of NO if the temperature is doubled? 2NOBr(g) ⇌ 2NO(g) + Br2(g)


A) The concentration of NO will increase.
B) The concentration of NO will decrease.
C) There will be no change in [NO].
D) A catalyst will be needed to make a change in concentration.
E) The change in concentration of [NO] will depend on the size of the vessel.

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A catalyst for a chemical reaction affects the magnitude of the equilibrium constant.

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At equilibrium, the concentrations of the reactants and products are always equal.

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The ________ is the energy difference between reactants and products in a chemical reaction.


A) transition energy
B) activation energy
C) product energy
D) overall energy
E) heat of reaction

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In a catalytic converter in an automobile, the reaction of carbon monoxide with oxygen produces


A) carbon dioxide.
B) carbon and more oxygen.
C) water.
D) methane.
E) nitrogen oxide.

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In the reaction of nitrogen and hydrogen to give ammonia, all the reactants and products are


A) gases.
B) liquids.
C) solids.
D) boiling.
E) frozen.

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Refrigerating perishable foods affects biochemical reactions by


A) increasing concentrations of antioxidants.
B) removing bacteria.
C) decreasing the rate of reactions affecting spoilage.
D) catalyzing the removal of harmful chemicals from the foods.
E) improving the appearance of the foods.

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An equilibrium in which all the components are gases is a ________ equilibrium.


A) heterogeneous
B) liquid
C) catalytic
D) homogeneous
E) reversible

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In the following gas phase reaction, what is the effect on the direction of the reaction if more SO₃ is added to the reaction mixture? 2SO2(g) + O2(g) ⇌ 2SO₃(g)


A) The equilibrium shifts to produce more products.
B) The position of the equilibrium remains unchanged.
C) The rate of formation of products is increased.
D) The equilibrium shifts to produce more reactants.
E) The catalyst for the reaction is used up.

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In the reaction of carbon dioxide with water to give carbonic acid, the only gaseous component is the carbon dioxide. What will happen to the equilibrium concentration of carbonic acid if the pressure of carbon dioxide is increased in the container?


A) The concentration of carbonic acid will increase.
B) The carbonic acid concentration will decrease.
C) The carbonic acid concentration will stay the same.
D) There will be twice as much carbonic acid as carbon dioxide.
E) There will be more water available for the reaction.

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The physiological equilibrium system that keeps the temperature of the body constant is called


A) stimulation.
B) regulation.
C) metabolism.
D) homeostasis.
E) catalysis.

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For the following reaction, the equilibrium constant Kc is 2.0 at a certain temperature. If the concentration of both products is 0.10 M at equilibrium, what is the concentration of the starting material, NOBr? 2NOBr(g) ⇌ 2NO(g) + Br2(g)


A) 5 × 10-4 M
B) 2.2 × 10-4 M
C) 5 × 10-2 M
D) 2.2 × 10-2 M
E) 2.2 M

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The equation for the formation of ammonia from nitrogen and hydrogen is shown below. What is the form of the equilibrium constant? 3H2(g) + N2(g) ⇌ 2NH₃(g)


A) The equation for the formation of ammonia from nitrogen and hydrogen is shown below. What is the form of the equilibrium constant?  3H2(g)  + N2(g)  ⇌ 2NH₃(g)  A)    B)    C)    D)    E)
B) The equation for the formation of ammonia from nitrogen and hydrogen is shown below. What is the form of the equilibrium constant?  3H2(g)  + N2(g)  ⇌ 2NH₃(g)  A)    B)    C)    D)    E)
C) The equation for the formation of ammonia from nitrogen and hydrogen is shown below. What is the form of the equilibrium constant?  3H2(g)  + N2(g)  ⇌ 2NH₃(g)  A)    B)    C)    D)    E)
D) The equation for the formation of ammonia from nitrogen and hydrogen is shown below. What is the form of the equilibrium constant?  3H2(g)  + N2(g)  ⇌ 2NH₃(g)  A)    B)    C)    D)    E)
E) The equation for the formation of ammonia from nitrogen and hydrogen is shown below. What is the form of the equilibrium constant?  3H2(g)  + N2(g)  ⇌ 2NH₃(g)  A)    B)    C)    D)    E)

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The reaction of hemoglobin with oxygen can be written as follows. Hb + O2 ⇌ HbO₂ If the amount of oxygen available to the blood decreases significantly, what happens to the individual involved?


A) Hypoxia results.
B) Anemia results.
C) Nitrogen narcosis results.
D) Oxygen poisoning results.
E) Acclimatization results.

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A chemical reaction has reached equilibrium when


A) the concentrations of reactants and products are equal.
B) all reactants have been converted to products.
C) all products have been removed from the reaction mixture.
D) the catalyst has been used up.
E) the rate of the forward reaction equals the rate of the reverse reaction.

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In an exothermic reaction, heat can be considered a


A) reactant.
B) product.
C) rate.
D) catalyst.
E) determinant.

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