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Which of the following used to be more precious than gold or silver,due to difficulties refining it?


A) copper
B) aluminum
C) tin
D) zinc
E) iron

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Copper is electroplated from CuSO4 solution.A constant current of 3.19 amp is applied by an external power supply.How long will it take to deposit 1.00 ×\times 102 g of Cu? The atomic mass of copper is 63.546.


A) 26.4 h
B) 13.2 min
C) 2.03 days
D) 9.57 s
E) 3.78 h

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Which of the following statements about batteries is false?


A) A battery is a group of galvanic cells connected in series.
B) Lead storage batteries contain lead at the anode and lead coated with lead dioxide at the cathode.
C) The alkaline dry cell battery can last longer than a nickel-cadmium battery.
D) A fuel cell is a galvanic cell for which the reactants are continuously supplied.
E) Dry cell batteries are used in tape players and portable radios.

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Which energy conversion shown below takes place in a galvanic cell?


A) electrical to chemical
B) chemical to electrical
C) mechanical to chemical
D) chemical to mechanical
E) mechanical to electrical

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When the following reaction is balanced in acidic solution,what is the coefficient of I2? IO3- + I- \to I2


A) 1
B) 2
C) 3
D) 4
E) none of these

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If an electrolysis plant operates its electrolytic cells at a total current of 1.8 ×\times 106 amp,how long will it take to produce one metric ton (one million grams) of Mg(s) from seawater containing Mg2+? (1 faraday = 96,485 coulombs)


A) 1.2 h
B) 1.2 days
C) 37 min
D) 0.61 h
E) 0.31 year

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A concentration cell is constructed with copper electrodes and Cu2+ in each compartment.In one compartment,the [Cu2+] = 1.0 ×\times 10-3 M and in the other compartment,the [Cu2+] = 2.0 M.Calculate the potential for this cell at 25°C.The standard reduction potential for Cu2+ is +0.34 V.


A) 0.44 V
B) -0.44 V
C) 0.098 V
D) -0.098 V
E) 0.78 V

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A cell is set up with copper and lead electrodes in contact with CuSO4(aq) and Pb(NO3) 2(aq) ,respectively,at 25°C.The standard reduction potentials are: Pb2+ + 2e- \to Pb ε\varepsilon \circ = -0.13 V Cu2+ + 2e- \to Cu ε\varepsilon \circ = +0.34 V If the Pb2+ and Cu2+ are each 1.0 M,the potential of the cell,in volts,is:


A) 0.47 V
B) 0.92 V
C) 0.22 V
D) 0.58 V
E) none of these

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Which of the following species cannot function as an oxidizing agent?


A) S(s)
B) NO3-(aq)
C) Cr2O72-(aq)
D) I-(aq)
E) MnO4-(aq)

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What is the oxidation state of Hg in Hg2Cl2?


A) +2
B) -1
C) -2
D) +1
E) 0

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A common car battery consists of six identical cells each of which carries out the reaction: Pb + PbO2 + 2HSO4- + 2H+ \to 2PbSO4 + 2H2O Suppose that in starting a car on a cold morning a current of 125 amperes is drawn for 18.4 seconds from a cell of the type described above.How many grams of Pb would be consumed? (The atomic weight of Pb is 207.19. )


A) 4.94 g
B) 2.47 g
C)  A common car battery consists of six identical cells each of which carries out the reaction: Pb + PbO<sub>2</sub> + 2HSO<sub>4</sub><sup>-</sup> + 2H<sup>+</sup>  \to  2PbSO<sub>4</sub> + 2H<sub>2</sub>O Suppose that in starting a car on a cold morning a current of 125 amperes is drawn for 18.4 seconds from a cell of the type described above.How many grams of Pb would be consumed? (The atomic weight of Pb is 207.19. )  A) 4.94 g B) 2.47 g C)    <sup> </sup>g D)    <sup> </sup>g E)    <sup> </sup>g g
D)  A common car battery consists of six identical cells each of which carries out the reaction: Pb + PbO<sub>2</sub> + 2HSO<sub>4</sub><sup>-</sup> + 2H<sup>+</sup>  \to  2PbSO<sub>4</sub> + 2H<sub>2</sub>O Suppose that in starting a car on a cold morning a current of 125 amperes is drawn for 18.4 seconds from a cell of the type described above.How many grams of Pb would be consumed? (The atomic weight of Pb is 207.19. )  A) 4.94 g B) 2.47 g C)    <sup> </sup>g D)    <sup> </sup>g E)    <sup> </sup>g g
E)  A common car battery consists of six identical cells each of which carries out the reaction: Pb + PbO<sub>2</sub> + 2HSO<sub>4</sub><sup>-</sup> + 2H<sup>+</sup>  \to  2PbSO<sub>4</sub> + 2H<sub>2</sub>O Suppose that in starting a car on a cold morning a current of 125 amperes is drawn for 18.4 seconds from a cell of the type described above.How many grams of Pb would be consumed? (The atomic weight of Pb is 207.19. )  A) 4.94 g B) 2.47 g C)    <sup> </sup>g D)    <sup> </sup>g E)    <sup> </sup>g g

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If a constant current of 5.0 amperes is passed through a cell containing Cr3+ for 1.0 hour,how many grams of Cr will plate out onto the cathode? (The atomic mass of Cr is 51.996. )


A) 9.7 g
B) If a constant current of 5.0 amperes is passed through a cell containing Cr<sup>3+</sup> for 1.0 hour,how many grams of Cr will plate out onto the cathode? (The atomic mass of Cr is 51.996. )  A) 9.7 g B)    <sup> </sup>g C) 3.2 g D) 29 g E)    <sup> </sup>g g
C) 3.2 g
D) 29 g
E) If a constant current of 5.0 amperes is passed through a cell containing Cr<sup>3+</sup> for 1.0 hour,how many grams of Cr will plate out onto the cathode? (The atomic mass of Cr is 51.996. )  A) 9.7 g B)    <sup> </sup>g C) 3.2 g D) 29 g E)    <sup> </sup>g g

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Consider the galvanic cell shown below (the contents of each half-cell are written beneath each compartment) :  Consider the galvanic cell shown below (the contents of each half-cell are written beneath each compartment) :   0.50 M Br<sub>2</sub> 0.20 M Cr<sup>3+</sup> 0.10 M Br<sup>-</sup> The standard reduction potentials are as follows: Cr<sup>3+</sup>(aq) + 3e<sup>-</sup>  \to  Cr(s)   \varepsilon <sup> \circ </sup> =-0.73 V Br<sub>2</sub>(aq) + 2e<sup>-</sup>  \to  2Br<sup>-</sup>(aq)   \varepsilon <sup> \circ </sup> = +1.09 V Which of the following statements about this cell is false? A) This is a galvanic cell. B) Electrons flow from the Pt electrode to the Cr electrode. C) Reduction occurs at the Pt electrode. D) The cell is not at standard conditions. E) To complete the circuit,cations migrate into the left half-cell and anions migrate into the right half-cell from the salt bridge. 0.50 M Br2 0.20 M Cr3+ 0.10 M Br- The standard reduction potentials are as follows: Cr3+(aq) + 3e- \to Cr(s) ε\varepsilon \circ =-0.73 V Br2(aq) + 2e- \to 2Br-(aq) ε\varepsilon \circ = +1.09 V Which of the following statements about this cell is false?


A) This is a galvanic cell.
B) Electrons flow from the Pt electrode to the Cr electrode.
C) Reduction occurs at the Pt electrode.
D) The cell is not at standard conditions.
E) To complete the circuit,cations migrate into the left half-cell and anions migrate into the right half-cell from the salt bridge.

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Balance the following equation: Zn + As2O3 \to AsH3 + Zn2+ (acid)

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12H+ + 6Zn + As2O<...

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The following question refers to the following system: 3Ag(s) + NO3-(aq) + 4H+(aq) \to 3Ag+(aq) + NO(g) + 2H2O(l) Anode reaction: Ag \to Ag+(aq) + e- ε\varepsilon \circ = -0.7990 V Cathode reaction: NO3-(aq) + 4H+(aq) + 3e- \to NO(g) + 2H2O(l) ε\varepsilon \circ = 0.9644 V Determine the standard cell potential.


A) -1.7634 V
B) 0.1654 V
C) 2.0942 V
D) 3.5268 V
E) 0.5878 V

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The following question refers to a galvanic cell that utilizes the following reaction (unbalanced) : (AuCl4) -(aq) + Cu(s) \to Au(s) + Cl-(aq) + Cu2+(aq) Given the following information,determine the standard cell potential: Species Standard Reduction Potential (V) Au3+(aq) 1.4980 Cu2+(aq)  The following question refers to a galvanic cell that utilizes the following reaction (unbalanced) : (AuCl<sub>4</sub>) <sup>-</sup>(aq) + Cu(s)  \to  Au(s) + Cl<sup>-</sup>(aq) + Cu<sup>2+</sup>(aq)  Given the following information,determine the standard cell potential: Species Standard Reduction Potential (V)  Au<sup>3+</sup>(aq)  1.4980 Cu<sup>2+</sup>(aq)    A) 1.1590 V B) 1.8370 V C) 3.8160 V D) 0.8200 V E) 4.1550 V


A) 1.1590 V
B) 1.8370 V
C) 3.8160 V
D) 0.8200 V
E) 4.1550 V

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An unknown metal (M) is electrolyzed.It took 74.1 s for a current of 2.00 amp to plate 0.107 g of the metal from a solution containing M(NO3) 3.Identify the metal.


A) La
B) Bi
C) Ga
D) Cu
E) Rh

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Which of the following statements is true about a voltaic cell for which ε\varepsilon °cell = 1.00 V?


A) It has Δ\Delta G° > 0.
B) The system is at equilibrium.
C) It has K = 1.
D) The cathode is at a higher energy than the anode.
E) The reaction is spontaneous.

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A concentration cell is constructed using two Ni electrodes with Ni2+ concentrations of 1.0 M and 1.00 ×\times 10-4 M in the two half-cells.The reduction potential of Ni2+ is -0.23 V.Calculate the potential of the cell at 25°C.


A) -0.368 V
B) +0.132 V
C) -0.132 V
D) +0.118 V
E) +0.0592 V

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How many seconds would it take to deposit 18.2 g of Ag (atomic mass = 107.87) from a solution of AgNO3 using a current of 10.00 amp?


A) How many seconds would it take to deposit 18.2 g of Ag (atomic mass = 107.87) from a solution of AgNO<sub>3</sub> using a current of 10.00 amp? A)    s B)    s C)    s D)    s E)    s s
B) How many seconds would it take to deposit 18.2 g of Ag (atomic mass = 107.87) from a solution of AgNO<sub>3</sub> using a current of 10.00 amp? A)    s B)    s C)    s D)    s E)    s s
C) How many seconds would it take to deposit 18.2 g of Ag (atomic mass = 107.87) from a solution of AgNO<sub>3</sub> using a current of 10.00 amp? A)    s B)    s C)    s D)    s E)    s s
D) How many seconds would it take to deposit 18.2 g of Ag (atomic mass = 107.87) from a solution of AgNO<sub>3</sub> using a current of 10.00 amp? A)    s B)    s C)    s D)    s E)    s s
E) How many seconds would it take to deposit 18.2 g of Ag (atomic mass = 107.87) from a solution of AgNO<sub>3</sub> using a current of 10.00 amp? A)    s B)    s C)    s D)    s E)    s s

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