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The acid dissociation constant Ka equals 1.26 × 10-2 for HSO4- and is 5.6 × 10-10 for NH4+. Which statement about the following equilibrium is correct? HSO4-(aq) + NH3(aq) The acid dissociation constant K<sub>a</sub> equals 1.26 × 10<sup>-2</sup> for HSO<sub>4</sub><sup>- </sup>and is 5.6 × 10<sup>-10 </sup>for NH<sub>4</sub><sup>+</sup>. Which statement about the following equilibrium is correct?  HSO<sub>4</sub><sup>-</sup>(aq)  + NH<sub>3</sub>(aq)    SO<sub>4</sub><sup>2-</sup>(aq)  + NH<sub>4</sub><sup>+</sup>(aq)  A)  The reactants will be favored because ammonia is a stronger base than the sulfate anion. B)  The products will be favored because the hydrogen sulfate ion is a stronger acid than the ammonium ion. C)  Neither reactants nor products will be favored because all of the species are weak acids or bases. D)  The initial concentrations of the hydrogen sulfate ion and ammonia must be known before any prediction can be made. E)  This reaction is impossible to predict, since the strong acid and the weak base appear on the same side of the equation. SO42-(aq) + NH4+(aq)


A) The reactants will be favored because ammonia is a stronger base than the sulfate anion.
B) The products will be favored because the hydrogen sulfate ion is a stronger acid than the ammonium ion.
C) Neither reactants nor products will be favored because all of the species are weak acids or bases.
D) The initial concentrations of the hydrogen sulfate ion and ammonia must be known before any prediction can be made.
E) This reaction is impossible to predict, since the strong acid and the weak base appear on the same side of the equation.

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The substance H2SO3 is considered


A) a weak Arrhenius base.
B) a strong Arrhenius acid.
C) a strong Arrhenius base.
D) a neutral compound.
E) a weak Arrhenius acid.

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What is the [OH-] for a solution at 25°C that has [H3O+] = 8.23 × 10-2 M?


A) > 10-5 M
B) 1.22 × 10-6 M
C) 8.23 × 10-12 M
D) 1.22 × 10-13 M
E) 8.23 × 10-16 M

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Which one of the following substances will give an aqueous solution of pH closest to 7?


A) KNO3
B) CO2
C) NH4I
D) NH3
E) CH3NH2

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The substance NaNO3 is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

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Arsenic acid, H3AsO4, is used industrially to manufacture insecticides. Arsenic acid is a polyprotic acid with K1 = 2.5 × 10-4, K2 = 5.6 × 10-8, and K3 = 3 × 10-13. What is the concentration of the HAsO42- in a solution whose initial arsenic acid concentration was 0.35 M?


A) 9.4 × 10-3 M
B) 2.5 × 10-4 M
C) 8.8 × 10-5 M
D) 5.6 × 10-8 M
E) none of the above

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Formic acid, which is a component of insect venom, has a Ka = 1.8 × 10-4. What is the [H3O+] in a solution that is initially 0.10 M formic acid, HCOOH?


A) 4.2 × 10-3 M
B) 8.4 × 10-3 M
C) 1.8 × 10-4 M
D) 1.8 × 10-5 M
E) 1.8 × 10-6 M

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What is the value of Ka for the methylammonium ion, CH3NH3+? Kb(CH3NH2) = 4.4 × 10-4


A) 4.4 × 10-4
B) 4.8 × 10-6
C) 4.4 × 10-10
D) 2.3 × 10-11
E) 4.4 × 10-18

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Which, if any, of the following acids is strong?


A) phosphoric
B) carbonic
C) acetic
D) water
E) none of the above

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Which one of the following will give a solution with a pH > 7, but is not an Arrhenius base in the strict sense?


A) CH3NH2
B) NaOH
C) CO2
D) Ca(OH) 2
E) CH4

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Calcium oxide, CaO, also known as quick lime, will react with carbon dioxide to form calcium carbonate, CaCO3. Which species, if any, acts as a Lewis acid in the reaction?


A) Ca2+
B) O2-
C) CO2
D) CaCO3
E) None of the species acts as a Lewis acid in this reaction.

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What is the value of Kb for the formate anion, HCOO-? Ka(HCOOH) = 2.1 × 10-4


A) -2.1 × 10-4
B) 2.1 × 10-4
C) 6.9 × 10-6
D) 4.8 × 10-11
E) 2.1 × 10-18

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The substance Ba(OH) 2 is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

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D

(a) Write a balanced equation representing the reaction of the acid, H2PO4- with the base, water. (b) Write the expression for Ka of H2PO4- in terms of concentrations of relevant species.

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(a) H2PO4-(aq...

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The substance HClO4 is considered


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

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C

According to Brønsted and Lowry, which one of the following is not a conjugate acid-base pair?


A) H3O+/OH-
B) CH3OH2+/CH3OH
C) HI/I-
D) HSO4-/SO42-
E) H2/H-

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Which one of the following pairs is not a conjugate acid-base pair?


A) H2O/OH-
B) H2O2/HO2-
C) OH-/O2-
D) H2PO4-/HPO42-
E) HCl/H+

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What is the pH of a 0.050 M triethylamine, (C2H5) 3N, solution? Kb for triethylamine is 5.3 × 10-4.


A) 11.69
B) 8.68
C) 5.32
D) 2.31
E) < 2.0

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A

An aqueous solution is considered to be acidic if


A) the hydroxide ion concentration is 10-6 M.
B) the hydrogen ion concentration is 10-8 M.
C) the hydroxide and hydrogen ion concentrations are equal.
D) the hydroxide ion concentration is greater than the hydrogen ion concentration.
E) the hydroxide ion concentration is 10-10 M.

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A 0.15 M solution of chloroacetic acid has a pH of 1.86. What is the value of Ka for this acid?


A) 7.2 × 101
B) 0.16
C) 0.099
D) 0.0014
E) 0.00027

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