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Label the axes on the UV-vis spectrum below. Label the axes on the UV-vis spectrum below.

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Which of the following stretching vibrations will appear at the highest frequency?


A) Which of the following stretching vibrations will appear at the highest frequency? A)    B)    C)    D)    E)
B) Which of the following stretching vibrations will appear at the highest frequency? A)    B)    C)    D)    E)
C) Which of the following stretching vibrations will appear at the highest frequency? A)    B)    C)    D)    E)
D) Which of the following stretching vibrations will appear at the highest frequency? A)    B)    C)    D)    E)
E) Which of the following stretching vibrations will appear at the highest frequency? A)    B)    C)    D)    E)

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Which of the following would you expect to have the longest λmax?


A) Which of the following would you expect to have the longest λ<sub>max</sub>? A)    B)    C)    D)    E)
B) Which of the following would you expect to have the longest λ<sub>max</sub>? A)    B)    C)    D)    E)
C) Which of the following would you expect to have the longest λ<sub>max</sub>? A)    B)    C)    D)    E)
D) Which of the following would you expect to have the longest λ<sub>max</sub>? A)    B)    C)    D)    E)
E) Which of the following would you expect to have the longest λ<sub>max</sub>? A)    B)    C)    D)    E)

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Which of the following compounds is consistent with the IR spectrum shown below? Which of the following compounds is consistent with the IR spectrum shown below?   A)    B)    C)    D)    E)


A) Which of the following compounds is consistent with the IR spectrum shown below?   A)    B)    C)    D)    E)
B) Which of the following compounds is consistent with the IR spectrum shown below?   A)    B)    C)    D)    E)
C) Which of the following compounds is consistent with the IR spectrum shown below?   A)    B)    C)    D)    E)
D) Which of the following compounds is consistent with the IR spectrum shown below?   A)    B)    C)    D)    E)
E) Which of the following compounds is consistent with the IR spectrum shown below?   A)    B)    C)    D)    E)

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Which of the following would show a C Which of the following would show a C   O stretch at the lowest frequency in its IR spectrum? A)    B)    C)    D)    E)   O stretch at the lowest frequency in its IR spectrum?


A) Which of the following would show a C   O stretch at the lowest frequency in its IR spectrum? A)    B)    C)    D)    E)
B) Which of the following would show a C   O stretch at the lowest frequency in its IR spectrum? A)    B)    C)    D)    E)
C) Which of the following would show a C   O stretch at the lowest frequency in its IR spectrum? A)    B)    C)    D)    E)
D) Which of the following would show a C   O stretch at the lowest frequency in its IR spectrum? A)    B)    C)    D)    E)
E) Which of the following would show a C   O stretch at the lowest frequency in its IR spectrum? A)    B)    C)    D)    E)

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Label the axes on the IR spectrum below. Label the axes on the IR spectrum below.

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What type of electron transition would create an absorption band at the longest wavelength in the UV-vis spectrum of the molecule below? What type of electron transition would create an absorption band at the longest wavelength in the UV-vis spectrum of the molecule below?   A)    B)    C)    D)    E)


A) What type of electron transition would create an absorption band at the longest wavelength in the UV-vis spectrum of the molecule below?   A)    B)    C)    D)    E)
B) What type of electron transition would create an absorption band at the longest wavelength in the UV-vis spectrum of the molecule below?   A)    B)    C)    D)    E)
C) What type of electron transition would create an absorption band at the longest wavelength in the UV-vis spectrum of the molecule below?   A)    B)    C)    D)    E)
D) What type of electron transition would create an absorption band at the longest wavelength in the UV-vis spectrum of the molecule below?   A)    B)    C)    D)    E)
E) What type of electron transition would create an absorption band at the longest wavelength in the UV-vis spectrum of the molecule below?   A)    B)    C)    D)    E)

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What is the approximate energy difference between the HOMO and LUMO of a molecule that shows absorption bands at 286 nm,438 nm,and 472 nm in its UV-vis spectrum?


A) 4.54 × 10-19 J
B) 6.95 × 10-19 J
C) 7.24 × 10-19 J
D) 3.98 × 10-19 J
E) 4.21 × 10-19 J

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Which of the following wavelengths corresponds to the photon with the highest energy?


A) 385 nm
B) 425 nm
C) 318 nm
D) 538 nm
E) 647 nm

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Briefly explain why acetone absorbs at a longer λmax than isobutylene. Briefly explain why acetone absorbs at a longer λ<sub>max</sub> than isobutylene.

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The HOMO of acetone is at a higher energ...

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An unknown compound has the molecular formula C3H7ON.Draw a structure of the unknown that is consistent with the IR spectrum below. An unknown compound has the molecular formula C<sub>3</sub>H<sub>7</sub>ON.Draw a structure of the unknown that is consistent with the IR spectrum below.

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Which of the following compounds would be consistent with the IR spectrum shown below? Briefly explain your reasoning. Which of the following compounds would be consistent with the IR spectrum shown below? Briefly explain your reasoning.

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Compound A is the most consistent with t...

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What carbonyl-containing functional group is indicated by the IR spectrum below? What carbonyl-containing functional group is indicated by the IR spectrum below?

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A compound whose molecular formula is C5H8O shows a strong absorption band at 1692 cm1.Draw a structure consistent with this information.

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Describe how you could use IR spectroscopy to distinguish between the two isomers shown below. Describe how you could use IR spectroscopy to distinguish between the two isomers shown below.

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Compound A should exhibit a carboxylic a...

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What two functional groups are likely indicated by the peaks labeled A and B in the IR spectrum below? What two functional groups are likely indicated by the peaks labeled A and B in the IR spectrum below?

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Peak A likely represents a pri...

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Which of the two isomers shown below would exhibit a stronger C Which of the two isomers shown below would exhibit a stronger C    C stretching absorption band? Explain your answer.  C stretching absorption band? Explain your answer. Which of the two isomers shown below would exhibit a stronger C    C stretching absorption band? Explain your answer.

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The isomer with the terminal alkene (B)w...

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Rank the following in order of increasing C Rank the following in order of increasing C   O stretching frequency.   A) 2 < 1 < 3 B) 3 < 1 < 2 C) 1 < 2 < 3 D) 2 < 3 < 1 E) 3 < 2 < 1 O stretching frequency. Rank the following in order of increasing C   O stretching frequency.   A) 2 < 1 < 3 B) 3 < 1 < 2 C) 1 < 2 < 3 D) 2 < 3 < 1 E) 3 < 2 < 1


A) 2 < 1 < 3
B) 3 < 1 < 2
C) 1 < 2 < 3
D) 2 < 3 < 1
E) 3 < 2 < 1

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Which of the following bonds would have the lowest stretching vibrational frequency?


A) Which of the following bonds would have the lowest stretching vibrational frequency? A)    B)    C)    D)    E)
B) Which of the following bonds would have the lowest stretching vibrational frequency? A)    B)    C)    D)    E)
C) Which of the following bonds would have the lowest stretching vibrational frequency? A)    B)    C)    D)    E)
D) Which of the following bonds would have the lowest stretching vibrational frequency? A)    B)    C)    D)    E)
E) Which of the following bonds would have the lowest stretching vibrational frequency? A)    B)    C)    D)    E)

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A compound has the molecular formula C7H6N2.Determine its structure based on the spectrum below. A compound has the molecular formula C<sub>7</sub>H<sub>6</sub>N<sub>2</sub>.Determine its structure based on the spectrum below.

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