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Identify the pericyclic reaction in which two sigma bonds are broken and two pi bonds are formed.


A) sigmatropic rearrangement
B) cycloaddition reaction
C) electrolytic reaction
D) this is not a pericyclic reaction

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Which diene and dienophile would react to give the following Diels-Alder product? Which diene and dienophile would react to give the following Diels-Alder product?     A)  I B)  II C)  III D)  IV Which diene and dienophile would react to give the following Diels-Alder product?     A)  I B)  II C)  III D)  IV


A) I
B) II
C) III
D) IV

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How many π\pi -bonding molecular orbitals does 1,3-pentadiene have?


A) 1
B) 2
C) 3
D) 4
E) none

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Which of the following compounds has the longest λ\lambda max?  Which of the following compounds has the longest  \lambda <sub>max</sub>?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

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Identify the light-sensitive compound in rods.

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Which one of the following dienes is least stable? Which one of the following dienes is least stable?   A)  I B)  II C)  III D)  IV


A) I
B) II
C) III
D) IV

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Compound A is one of the intermediate products in the synthesis of the corticoid hormone cortisone. Provide the structure of compound A. Compound A is one of the intermediate products in the synthesis of the corticoid hormone cortisone. Provide the structure of compound A.

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What is the correct classification of the following pericyclic reaction? What is the correct classification of the following pericyclic reaction?   A)  electrophilic addition B)  sigmatropic rearrangement C)  cycloaddition D)  electrocyclic reaction E)  C & D


A) electrophilic addition
B) sigmatropic rearrangement
C) cycloaddition
D) electrocyclic reaction
E) C & D

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Which of the following symbols is used to represent the molar absorptivity of a given compound in the UV-Vis region?


A) ( λ\lambda )
B) ( ε\varepsilon )
C) ( vv )
D) ( γ\gamma )
E) ( α\alpha )

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Which diene and dienophile would react to give the following Diels-Alder product? Which diene and dienophile would react to give the following Diels-Alder product?

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Which diene and dienophile would react to give the following Diels-Alder product? Which diene and dienophile would react to give the following Diels-Alder product?

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What is the Cope rearrangement?


A) [2,2] sigmatropic rearrangement with all atoms of the cyclic transition step are carbon atoms
B) [2,2] sigmatropic rearrangement with heteroatoms
C) [2,3] sigmatropic rearrangement with all atoms of the cyclic transition step are carbon atoms
D) [2,3] sigmatropic rearrangement with heteroatoms
E) [3,3] sigmatropic rearrangement with all atoms of the cyclic transition step are carbon atoms

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Predict the product for the following Diels-Alder reaction. Predict the product for the following Diels-Alder reaction.     A)  I B)  II C)  III D)  IV E)  None of these Predict the product for the following Diels-Alder reaction.     A)  I B)  II C)  III D)  IV E)  None of these


A) I
B) II
C) III
D) IV
E) None of these

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Predict the product for the following Cope rearrangement. Predict the product for the following Cope rearrangement.      A. I B. II C. III D. IV Predict the product for the following Cope rearrangement.      A. I B. II C. III D. IV A. I B. II C. III D. IV

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C
Describe the defining featur...

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Predict the major product for the following reaction and explain why it is major product. Predict the major product for the following reaction and explain why it is major product.

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blured image_TB4454_00 This reaction is under thermo...

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The polymerization of isoprene to produce synthetic rubber is a special case of ____- addition.

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Predict the product(s) for the following reaction. Predict the product(s) for the following reaction.

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Which diene and dienophile would react to give the following Diels-Alder product? Which diene and dienophile would react to give the following Diels-Alder product?

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Which of the following compounds has the longest l λ\lambda max?  Which of the following compounds has the longest l \lambda <sub>max</sub>?   A)  I B)  II C)  III D)  IV E)  V


A) I
B) II
C) III
D) IV
E) V

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Which diene and dienophile would react to give the following Diels-Alder product? Which diene and dienophile would react to give the following Diels-Alder product?

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