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Place the following substances in order of increasing boiling point. CH3CH2OH \quad Ar \quad CH3OCH3


A) Ar < CH3OCH3 < CH3CH2OH
B) CH3CH2OH < Ar < CH3OCH3
C) CH3CH2OH < CH3OCH3 < Ar
D) CH3OCH3 < Ar < CH3CH2OH
E) Ar < CH3CH2OH < CH3OCH3

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Which of the following substances would you predict to have the highest ΔvapH?


A) Xe
B) C6H6
C) SiF4
D) Br2
E) N2

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Which one of the following has a definite shape and volume?


A) gas
B) liquid
C) solid
D) none of the above

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Describe the difference between the conduction band and the valence band.

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The valence band is the group of highest...

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NaCl crystallizes in a cubic unit cell with Cl- ions on each corner and each face.How many Na+ and Cl- ions are in each unit cell of NaCl?


A) 1 Na+ ion and 1 Cl- ion
B) 2 Na+ ions and 2 Cl- ions
C) 4 Na+ ions and 4 Cl- ions
D) 8 Na+ ions and 8 Cl- ions

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Ethanol ( C2H5OH) melts at -114 °C.The enthalpy of fusion is 5.02 kJ mol-1.The specific heats of solid and liquid ethanol are 0.97 J g-1 °C-1 and 2.3 J g-1 °C-1,respectively.How much heat (kJ) is needed to convert 25.0 g of solid ethanol at -145 °C to liquid ethanol at -60 °C?


A) 6.58
B) 9.96
C) 8.88
D) 3859
E) -13.56

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At atmospheric pressure,dry ice ________.


A) freezes
B) deposits
C) sublimes
D) melts
E) boils

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The normal boiling point of water is ________.


A) 0 °C
B) 32 °C
C) 212 °C
D) 100 °C
E) 273 °C

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Choose the molecule or compound that exhibits dispersion forces as its strongest intermolecular force.


A) Cl2
B) NH3
C) HF
D) NaCl

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Identify the compound that does not have hydrogen bonding.


A) (CH3) 3N
B) H2O
C) CH3OH
D) HF
E) CH3NH2

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Identify the compound that does not have dipole-dipole forces as its strongest force.


A) CH2Cl2
B) CH3OCH3
C) CH3Br
D) HCCl3
E) CO2

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Choose the pair of substances that are most likely to form a homogeneous solution.


A) NaCl and Hg
B) LiF and C6H14
C) C3H8 and C2H5OH
D) Br2 and PF3
E) NH3 and CH3OH

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Place the following compounds in order of decreasing strength of intermolecular forces. I.CH3CH2CH2CH2CH2CH3 \quad II.(CH3) 3CCH3 \quad III.(CH3) 3CCH2CH3


A) III > II > I
B) I > III > II
C) I > II > III
D) II > III > I
E) III > I > II

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Give the edge length in terms of r for a simple cubic cell.

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How much energy is required to vaporize 48.7 g of dichloromethane (CH2Cl2) at its boiling point if its ΔvapH is 31.6 kJ mol-1?


A) 31.2 kJ
B) 6.49 kJ
C) 55.1 kJ
D) 15.4 kJ
E) 18.1 kJ

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Choose the pair of substances that are most likely to form a homogeneous solution.


A) C6H14 and C10H20
B) LiBr and C5H12
C) N2O4 and NH4Cl
D) C6H14 and H2O
E) None of the pairs above will form a homogeneous solution.

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What is the strongest type of intermolecular force present in H2?


A) ion-dipole
B) dipole-dipole
C) dispersion
D) hydrogen bonding
E) none of the above

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Choose the substance with the highest vapour pressure at a given temperature.


A) SiS2
B) RbCl
C) CH3SCH3
D) BF3
E) SbH3

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Identify the term used to describe the ability of a liquid to flow against gravity up a narrow tube.


A) capillary action
B) viscosity
C) surface tension
D) density

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How much energy is required to vaporize 158 g of butane (C4H10) at its boiling point if its ΔvapH is 24.3 kJ mol-1?


A) 15.1 kJ
B) 66.1 kJ
C) 89.4 kJ
D) 11.2 kJ
E) 38.4 kJ

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