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The half-life of a first-order reaction is 13 min. If the initial concentration of reactant is 0.13 M, it takes __________ min for it to decrease to 0.085 M.


A) 12
B) 10
C) 8.0
D) 11
E) 7.0

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The concentration of S2O82- remaining at 400 s is __________ M.


A) +0.015
B) +0.035
C) -0.007
D) +0.045
E) +0.057

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The magnitude of the rate constant is __________.


A) 38.0
B) 0.278
C) 13.2
D) 42.0
E) 2.21

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The average rate of disappearance of I- in the initial 400.0 s is __________ M/s.


A) 6.00
B) 3.8 × 10-5
C) 1.4 × 10-4
D) 2.7 × 104
E) 3.2 × 10-4

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The following reaction is second order in [A] and the rate constant is 0.039 M-1s-1: A → B The concentration of A was 0.30 M at 23 s. The initial concentration of A was __________ M.


A) 2.4
B) 0.27
C) 0.41
D) 3.7
E) 1.2 × 10-2

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The average rate of disappearance of A between 20 s and 40 s is __________ mol/s.


A) 8.5 × 10-4
B) 1.7 × 10-3
C) 590
D) 7.1 × 10-3
E) 1.4 × 10-3

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The decomposition of N2O5 in solution in carbon tetrachloride proceeds via the reaction 2N2O5 (soln) → 4NO2 (soln) + O2 (soln) The reaction is first order and has a rate constant of 4.82 × 10-3 s-1 at 64°C. The rate law for the reaction is rate = __________.


A) k[N2O5]2
B) The decomposition of N<sub>2</sub>O<sub>5</sub> in solution in carbon tetrachloride proceeds via the reaction 2N<sub>2</sub>O<sub>5 </sub>(soln) → 4NO<sub>2 </sub>(soln) + O<sub>2 </sub>(soln)  The reaction is first order and has a rate constant of 4.82 × 10<sup>-3</sup> s<sup>-1</sup> at 64°C. The rate law for the reaction is rate = __________. A) k[N<sub>2</sub>O<sub>5</sub>]<sup>2</sup> B)    C) k[N<sub>2</sub>O<sub>5</sub>] D)    E) 2k[N<sub>2</sub>O<sub>5</sub>]
C) k[N2O5]
D) The decomposition of N<sub>2</sub>O<sub>5</sub> in solution in carbon tetrachloride proceeds via the reaction 2N<sub>2</sub>O<sub>5 </sub>(soln) → 4NO<sub>2 </sub>(soln) + O<sub>2 </sub>(soln)  The reaction is first order and has a rate constant of 4.82 × 10<sup>-3</sup> s<sup>-1</sup> at 64°C. The rate law for the reaction is rate = __________. A) k[N<sub>2</sub>O<sub>5</sub>]<sup>2</sup> B)    C) k[N<sub>2</sub>O<sub>5</sub>] D)    E) 2k[N<sub>2</sub>O<sub>5</sub>]
E) 2k[N2O5]

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The combustion of ethylene proceeds by the reaction C2H4 (g) + 3O2 (g) → 2CO2 (g) + 2H2O (g) When the rate of disappearance of O2 is 0.23 Ms-1, the rate of disappearance of C2H4 is __________ Ms-1.


A) 0.15
B) 0.077
C) 0.69
D) 0.35
E) 0.46

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Reaction rates are affected by reactant concentrations and temperature. This is accounted for by the __________.

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Which energy difference in the energy profile below corresponds to the activation energy for the forward reaction? Which energy difference in the energy profile below corresponds to the activation energy for the forward reaction?   A) x B) y C) x + y D) x - y E) y - x


A) x
B) y
C) x + y
D) x - y
E) y - x

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