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What is the solubility product expression for Pb(IO3) 4?


A) Ksp = [Pb4+][4IO3-]4
B) Ksp = [Pb4+][IO3-]
C) Ksp = [Pb][IO3]4
D) Ksp = [Pb4+][IO3-]4

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Silver nitrate (AgNO3) is slowly added to a solution containing 0.100 M Br− and 0.050 M FeCN64 until a precipitate just forms.What is the molar concentration of Ag+ just as the precipitate forms? AgBr Ksp = 5.0 × 10-13 and Ag4FeCN6 Ksp = 8.5 × 10-45.


A) 2.0 × 10-11 M Ag+
B) 5.0 × 10-12 M Ag+
C) 1.0 × 10-11 M Ag+
D) 3.3 × 10-12 M Ag+
E) 1.7 × 10-43 M Ag+

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What is the concentration of silver(I) ion in a saturated solution of silver(I) carbonate containing 0.0046 M Na2CO3? For Ag2CO3,Ksp = 8.6 × 10-12.


A) 6.0 × 10-4 M
B) 2.0 × 10-9 M
C) 8.0 × 10-9 M
D) 4.3 × 10-5 M
E) 8.0 × 10-4 M

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The following reaction represents a step in the separation of which analytical group of cations? Hg22+(aq) + 2Cl-(aq) → Hg2Cl2(s)


A) Analytical Group II
B) Analytical Group I
C) Analytical Group V
D) Analytical Group IV
E) Analytical Group III

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In which of these solutions would silver(I) carbonate have the lowest molar solubility? For silver(I) carbonate,Ksp = 8.5 × 10-12.


A) 0.03 M H2CO3
B) 0.1 M AgNO3
C) 0.01 M AgNO3
D) 0.1 M Na2CO3
E) pure water

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What is the molar solubility of lead(II) sulfate at 25°C? The solubility product constant for lead(II) sulfate is 1.7 × 10-8 at 25°C.


A) 1.7 × 10-8 M
B) 5.7 × 10-3 M
C) 8.5 × 10-9 M
D) 1.6 × 10-3 M
E) 1.3 × 10-4 M

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If 370 mL of 1 × 10-8 M Al(NO3) 3 is mixed with 370 mL of 1 × 10-8 M NaOH,what will occur? For Al(OH) 3,Ksp = 4.6 × 10-33.


A) Aluminum hydroxide will precipitate.
B) Sodium hydroxide will precipitate.
C) Aluminum nitrate will precipitate.
D) Sodium nitrate will precipitate.
E) No precipitate will form.

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What is the solubility product expression for mercury(I) chloride,Hg2Cl2?


A) Ksp = [Hg22+][2Cl-]2
B) Ksp = [Hg22+][Cl-]2
C) Ksp = [Hg22+][2Cl- ]
D) Ksp = [Hg2][Cl2]
E) Ksp = [Hg+]2[Cl-]2

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The hydroxide ion concentration of a saturated solution of Cu(OH) 2 is The hydroxide ion concentration of a saturated solution of Cu(OH) <sub>2</sub> is   M.What is the solubility product constant for Cu(OH) <sub>2</sub>? A)    B)    C)    D)    E)   M.What is the solubility product constant for Cu(OH) 2?


A) The hydroxide ion concentration of a saturated solution of Cu(OH) <sub>2</sub> is   M.What is the solubility product constant for Cu(OH) <sub>2</sub>? A)    B)    C)    D)    E)
B) The hydroxide ion concentration of a saturated solution of Cu(OH) <sub>2</sub> is   M.What is the solubility product constant for Cu(OH) <sub>2</sub>? A)    B)    C)    D)    E)
C) The hydroxide ion concentration of a saturated solution of Cu(OH) <sub>2</sub> is   M.What is the solubility product constant for Cu(OH) <sub>2</sub>? A)    B)    C)    D)    E)
D) The hydroxide ion concentration of a saturated solution of Cu(OH) <sub>2</sub> is   M.What is the solubility product constant for Cu(OH) <sub>2</sub>? A)    B)    C)    D)    E)
E) The hydroxide ion concentration of a saturated solution of Cu(OH) <sub>2</sub> is   M.What is the solubility product constant for Cu(OH) <sub>2</sub>? A)    B)    C)    D)    E)

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Figures I-IV represent ionic compounds formed upon the mixing of an aqueous solution containing cation C with an aqueous solution containing anion A.Identify the figure(s) that represent(s) products for which Ksp = 4s3,where s is the molar solubility of the ionic compound. Figures I-IV represent ionic compounds formed upon the mixing of an aqueous solution containing cation C with an aqueous solution containing anion A.Identify the figure(s) that represent(s) products for which K<sub>sp</sub> = 4s<sup>3</sup>,where s is the molar solubility of the ionic compound.   A) both I and II B) only II C) only IV D) only I E) only III


A) both I and II
B) only II
C) only IV
D) only I
E) only III

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Solid KCN is added to a solution composed of 0.10 M Ag+ and 0.10 M Zn2+ just until a precipitate forms.What is the composition of this initial precipitate? AgCN Ksp = 2.2 × 10-16 and Zn(CN) 2 Ksp = 3 × 10-16.


A) The precipitate is pure AgCN(s) .
B) The precipitateis pure Zn(CN) 2(s) .
C) The precipitate is a mixture of AgCN(s) and Zn(CN) 2(s) .
D) The precipitate is a mixture of KCN(s) and AgCN(s) .
E) The precipitate is a mixture of KCN(s) and Zn(CN) 2(s) .

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What is the molar solubility of zinc hydroxide at pH 12.34? For Zn(OH) 2,Ksp = 2.1 × 10-16; for Zn(OH) 42-,Kf = 2.8 × 1015.


A) 1.2 × 10-25 M
B) 1.3 × 10-2 M
C) 2.8 × 10-4 M
D) 3.7 × 10-6 M
E) 1.4 × 10-8 M

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The concentration of barium carbonate in a saturated aqueous solution of the salt at 25°C is The concentration of barium carbonate in a saturated aqueous solution of the salt at 25°C is   M.What is the K<sub>sp</sub> of this sparingly soluble salt? A)    B)    C)    D)    E)   M.What is the Ksp of this sparingly soluble salt?


A) The concentration of barium carbonate in a saturated aqueous solution of the salt at 25°C is   M.What is the K<sub>sp</sub> of this sparingly soluble salt? A)    B)    C)    D)    E)
B) The concentration of barium carbonate in a saturated aqueous solution of the salt at 25°C is   M.What is the K<sub>sp</sub> of this sparingly soluble salt? A)    B)    C)    D)    E)
C) The concentration of barium carbonate in a saturated aqueous solution of the salt at 25°C is   M.What is the K<sub>sp</sub> of this sparingly soluble salt? A)    B)    C)    D)    E)
D) The concentration of barium carbonate in a saturated aqueous solution of the salt at 25°C is   M.What is the K<sub>sp</sub> of this sparingly soluble salt? A)    B)    C)    D)    E)
E) The concentration of barium carbonate in a saturated aqueous solution of the salt at 25°C is   M.What is the K<sub>sp</sub> of this sparingly soluble salt? A)    B)    C)    D)    E)

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What is the solubility product expression for Al(OH) 3?


A) Ksp = [Al3+][3OH-]
B) Ksp = 3[Al3+][OH-]3
C) Ksp = [Al3+][OH-]3
D) Ksp = [Al3+][3OH-]3
E) Ksp = [Al3+][OH-]

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A _____ is an ion formed from a metal ion with a Lewis base attached to it by a coordinate covalent bond.


A) naive ion​
B) radical ion​
C) simple ion​
D) monatomic ion​
E) ​complex ion

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Suppose hydrogen sulfide is added to a solution that is 0.10 M in Cu2+,Pb2+,and Ni2+ such that the concentration of H2S is 0.10 M.When the pH of the solution is adjusted to 1.00,a precipitate forms.What is the composition of the precipitate? H2S(aq) + 2H2O(l) Suppose hydrogen sulfide is added to a solution that is 0.10 M in Cu<sup>2+</sup>,Pb<sup>2+</sup>,and Ni<sup>2+</sup> such that the concentration of H<sub>2</sub>S is 0.10 M.When the pH of the solution is adjusted to 1.00,a precipitate forms.What is the composition of the precipitate? H<sub>2</sub>S(aq) + 2H<sub>2</sub>O(l)    2H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) ; K<sub>c</sub> = 1.1 × 10<sup>-20</sup> Salt K<sub>sp</sub> CuS 6) 0 × 10<sup>-36</sup> PbS 2) 5 × 10<sup>-27</sup> NiS 3) 0 × 10<sup>-19</sup> A) CuS only B) PbS and NiS C) CuS and PbS D) NiS only E) CuS,PbS,and NiS 2H3O+(aq) + S2-(aq) ; Kc = 1.1 × 10-20 Salt Ksp CuS 6) 0 × 10-36 PbS 2) 5 × 10-27 NiS 3) 0 × 10-19


A) CuS only
B) PbS and NiS
C) CuS and PbS
D) NiS only
E) CuS,PbS,and NiS

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Suppose hydrogen sulfide is added to a solution that is 0.0010 M in Fe2+,Cd2+,Co2+,and Mn2+ such that the concentration of H2S is 0.10 M.When the pH of the solution is adjusted to 3,a precipitate forms.What is the composition of the precipitate? H2S(aq) + 2H2O(l) Suppose hydrogen sulfide is added to a solution that is 0.0010 M in Fe<sup>2+</sup>,Cd<sup>2+</sup>,Co<sup>2+</sup>,and Mn<sup>2+</sup> such that the concentration of H<sub>2</sub>S is 0.10 M.When the pH of the solution is adjusted to 3,a precipitate forms.What is the composition of the precipitate? H<sub>2</sub>S(aq) + 2H<sub>2</sub>O(l)    2H<sub>3</sub>O<sup>+</sup>(aq) + S<sup>2-</sup>(aq) ; K<sub>c</sub> = 1.1 × 10<sup>-20</sup> Salt K<sub>sp</sub> FeS 6) 0 × 10<sup>-18</sup> CdS 8) 0 × 10<sup>-27</sup> CoS 4) 0 × 10<sup>-21</sup> MnS 2) 5 × 10<sup>-10</sup> A) CdS only B) CdS,CoS,FeS,and MnS C) CdS,CoS,and FeS D) CdS and FeS E) CdS and CoS 2H3O+(aq) + S2-(aq) ; Kc = 1.1 × 10-20 Salt Ksp FeS 6) 0 × 10-18 CdS 8) 0 × 10-27 CoS 4) 0 × 10-21 MnS 2) 5 × 10-10


A) CdS only
B) CdS,CoS,FeS,and MnS
C) CdS,CoS,and FeS
D) CdS and FeS
E) CdS and CoS

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Given the two equilibria below, Ag(NH3) 2+(aq) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)   Ag+(aq) + 2NH3(aq) ; Kd = 5.9 × 10-8AgI(s) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)   Ag+(aq) + I−(aq) ; Ksp = Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)   What is Kc for the following equilibrium?AgI(s) + 2NH3(aq) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)   Ag(NH3) 2+(aq) + I-(aq)


A) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)
B) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)
C) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)
D) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)
E) Given the two equilibria below, Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)   Ag<sup>+</sup>(aq) + 2NH<sub>3</sub>(aq) ; K<sub>d</sub> = 5.9 × 10<sup>-8</sup>AgI(s)    Ag<sup>+</sup>(aq) + I−(aq) ; K<sub>sp</sub> =   What is K<sub>c</sub> for the following equilibrium?AgI(s) + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq) + I<sup>-</sup>(aq)  A)    B)    C)    D)    E)

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Which of the following is not likely to form a complex ion with Al3+?


A) NH4+
B) NH3
C) OH−
D) H2O
E) CH3NH2

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After mixing an excess PbCl2 with a fixed amount of water,it is found that the equilibrium concentration of Pb2+ is 1.6 × 10-2 M.What is Ksp for PbCl2?


A) 4.0 × 10-6
B) 1.6 × 10-5
C) 2.5 × 10-4
D) 4.8 × 10-2
E) 1.0 × 10-6

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