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Which statement concerning the vapor pressures of water and methanol (CH3OH) is ?


A) At 25ºC, methanol has a higher vapor pressure than water because methanol has a lower normal boiling point than water.
B) At 25ºC, methanol has a higher vapor pressure than water because methanol is a poorer solvent than water.
C) At 25ºC, methanol has a higher vapor pressure than water because methanol is a less viscous liquid than water.
D) At 25ºC, methanol has a higher vapor pressure than water because the density of methanol is less than the density of water.
E) At 25ºC, methanol has a higher vapor pressure than water because methanol has weaker intermolecular forces than water.

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What amount of energy (heat) is required to warm a 73.5-g sample of liquid ethanol from 15.0ºC to 29.5ºC? The specific heat capacity of ethanol is 2.46 J/gºC.


A) 0.485 J
B) 433 J
C) 2.62 × 103 J
D) 5.33 × 103 J
E) 238 J

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Which of the substances would form an ionic solid?


A) NCl3
B) NH4Cl
C) Ag
D) He
E) OF2

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Which state of matter is described as taking on the shape of its container, but having a specific volume?


A) solid
B) liquid
C) gas
D) solution
E) mixture

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Ethanol (C2H5-OH) will have a greater viscosity than ethylene glycol (HO-CH2CH2-OH) at the same temperature.

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What is the process in which molecules undergo a phase change from the solid phase to the liquid phase?


A) vaporization
B) condensation
C) freezing
D) melting
E) sublimation

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The specific heat (capacity) is


A) amount of energy needed to change 1 g of a substance by 1°C.
B) amount of energy needed to change 1 mol of a substance by 1°C
C) amount of energy required to melt 1 g of substance.
D) amount of substance that is heated by 1°C.
E) the temperature increase, in K, associated with heating 1 g of a substance for 1 minute.

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How much heat is required to raise the temperature of 1500 g of water from 25°C to 52°C? The specific heat of water is 4.184 J/g·°C.


A) 1500 kJ
B) 170 kJ
C) 6.3 kJ
D) 41 J
E) 41 kJ

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Which substance has the lowest vapor pressure at room temperature?


A) HF
B) HCl
C) HBr
D) HI
E) H2

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Which of the substances would form a metallic solid?


A) NCl3
B) KCl
C) Ni
D) Ar
E) MgF2

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Which corresponds to the temperature-dependent partial pressure above the surface of a liquid?


A) Surface tension
B) Vapor pressure
C) Boiling point
D) Viscosity
E) Capillary action

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If 325 g of water at 4.2°C absorbs 12.28 kJ, what is the final temperature of the water? The specific heat of water is 4.184 J/g·°C.


A) 4.21°C
B) 4.8°C
C) 9.0°C
D) 13.2°C
E) 2938°C

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Which of the following statements is ?


A) The higher the viscosity, the faster a liquid flows.
B) The viscosity increases with increasing temperature.
C) The stronger the intermolecular forces, the higher the viscosity.
D) Hydrogen bonding in water gives rise to its unusually low viscosity.
E) The viscosity of gases is larger than the viscosity of liquids.

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What is the process in which molecules undergo a phase change from the liquid phase to the gas phase?


A) vaporization
B) condensation
C) freezing
D) melting
E) sublimation

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Place the substances in order of decreasing boiling point. CO2 CH4 OF2


A) OF2 > CO2 > CH4
B) CH4 > CO2 > OF2
C) OF2 > CH4 > CO2
D) CO2 > CH4 > OF2
E) CO2 > OF2 > CH4

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Which of the following lacks a regular three-dimensional arrangement of atoms?


A) crystalline solids
B) ionic crystals
C) solids
D) amorphous solids
E) molecular solids

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Place the substances in order of increasing boiling point. BeF2 SF2 Ar


A) BeF2 < SF2 < Ar
B) Ar < BeF2 < SF2
C) SF2 < Ar < BeF2
D) SF2 < BeF2 < Ar
E) Ar < SF2 < BeF2

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Ammonia's unusually high melting point is the result of


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) covalent bonding.
E) ionic bonding.

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The energy required to increase the surface of a liquid per unit area is called the


A) capillary action.
B) surface tension.
C) viscosity.
D) cohesion.
E) specific elasticity.

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Benzene is a starting material in the synthesis of nylon fibers and polystyrene (styrofoam) .Its specific heat capacity is 1.74 J/g·°C.If 16.7 kJ of energy is absorbed by a 225-g sample of benzene at 20.0°C, what is its final temperature?


A) −22.7°C
B) 37.7°C
C) 42.7°C
D) 62.7°C
E) 80.1°C

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