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Which of the following solutions is a good buffer system?


A) a solution that is 0.10 M NaCl and 0.10 M HCl
B) a solution that is 0.10 M HCN and 0.10 M LiCN
C) a solution that is 0.10 M LiOH and 0.10 M HNO3
D) a solution that is 0.10 M HNO3 and 0.10 M LiNO3
E) a solution that is 0.10 M HCN and 0.10 M KBr

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Define buffer capacity.


A) Buffer capacity is the amount of acid or base that can be added to a buffer without destroying its effectiveness.
B) Buffer capacity is the amount of acid that can be added until all of the base is used up.
C) Buffer capacity is the amount of base that can be added until all of the acid is used up.
D) Buffer capacity is the amount of acid that can be added until all of the acid is used up.
E) Buffer capacity is the amount of base that can be added until all of the base is used up.

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A 100.0 mL sample of 0.20 M HF is titrated with 0.10 M KOH.Determine the pH of the solution before the addition of any KOH.The Ka of HF is 3.5 × 10-4.


A) 4.15
B) 0.70
C) 2.08
D) 3.46
E) 1.00

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What is the pH of a buffer solution that is 0.255 M in hypochlorous acid (HClO) and 0.333 M in sodium hypochlorite? The Ka of hypochlorous acid is 3.8 × 10-8.


A) 13.88
B) 6.46
C) 8.49
D) 7.30
E) 7.54

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Define a complex ion

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A complex ion contai...

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What is the molar solubility of AgCl in 0.30 M NH3? Ksp for AgCl is 1.8 × 10-10 and Kf for Ag(NH3) 2+ is 1.7 × 107.


A) 1.3 × 10-5 M
B) 1.6 × 10-2 M
C) 1.7 × 10-2 M
D) 5.5 × 10-2 M

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When titrating a strong monoprotic acid and KOH at 25°C,the


A) pH will be less than 7 at the equivalence point.
B) pH will be greater than 7 at the equivalence point.
C) titration will require more moles of base than acid to reach the equivalence point.
D) pH will be equal to 7 at the equivalence point.
E) titration will require more moles of acid than base to reach the equivalence point.

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Determine the molar solubility of Co3(AsO4) 2 in pure water.Ksp (Co3(AsO4) 2) = 6.80 × 10-29.


A) 2.02 × 10-5
B) 2.32 × 10-6
C) 2.15 × 10-8
D) 9.26 × 10-6
E) 9.12 × 10-7

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A solution is prepared by dissolving 0.23 mol of benzoic acid and 0.27 mol of sodium benzoate in water sufficient to yield 1.00 L of solution.The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly.The pH does not decrease drastically because the HCl reacts with the ________ present in the buffer solution.The Ka of benzoic acid is 1.36 × 10-3.


A) H2O
B) H3O+
C) benzoate ion
D) benzoic acid
E) This is a buffer solution: the pH does not change upon addition of acid or base.

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A 100.0 mL sample of 0.10 M NH3 is titrated with 0.10 M HNO3.Determine the pH of the solution after the addition of 50.0 mL of HNO3.The Kb of NH3 is 1.8 × 10-5.


A) 4.74
B) 7.78
C) 7.05
D) 9.26
E) 10.34

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A 100.0 mL sample of 0.18 M HClO4 is titrated with 0.27 M LiOH.Determine the pH of the solution after the addition of 30.0 mL of LiOH.


A) 0.86
B) 1.21
C) 2.00
D) 1.12
E) 2.86

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If the pKa of HCHO2 is 3.74 and the pH of an HCHO2/NaCHO2 solution is 3.11,which of the following is true?


A) [HCHO2] < [NaCHO2]
B) [HCHO2] = [NaCHO2]
C) [HCHO2] << [NaCHO2]
D) [HCHO2] > [NaCHO2]
E) It is not possible to make a buffer of this pH from HCHO2 and NaCHO2.

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Calculate the pH of a solution formed by mixing 250.0 mL of 0.15 M NH4Cl with 100.0 mL of 0.20 M NH3.The Kb for NH3 is 1.8 × 10-5.


A) 9.13
B) 9.25
C) 9.53
D) 4.74
E) 8.98

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Calculate the pH of a buffer that is 0.058 M HF and 0.058 M LiF.The Ka for HF is 3.5 × 10-4.


A) 2.86
B) 9.31
C) 10.54
D) 3.46
E) 4.69

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Match the following. -pH > 7


A) half-way to equivalence point of a weak acid/strong base titration
B) equivalence point of a strong acid/strong base titration
C) equivalence point of a weak base/strong acid titration
D) equivalence point of a weak acid/strong base titration

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An aqueous solution of 0.01 M NaCl and 0.01 M AgNO3 are mixed.Which statement is true? (Ksp of AgCl = 1.8 × 10-10)


A) A precipitate of AgCl will form.
B) No precipitate will form.
C) The solution will not have any Ag+ and Cl- ions after precipitation.
D) None of the above

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A 100.0 mL sample of 0.10 M Ca(OH) 2 is titrated with 0.10 M HBr.Determine the pH of the solution after the addition of 100.0 mL HBr.


A) 2.00
B) 12.00
C) 1.30
D) 12.70
E) 7.00

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What is the molar solubility of barium fluoride (BaF2) in water? The solubility-product constant for BaF2 is 1.7 × 10-6 at 25°C.


A) 6.5 × 10-4
B) 1.2 × 10-2
C) 1.8 × 10-3
D) 7.5 × 10-3
E) 5.7 × 10-7

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Calculate the percent ionization of nitrous acid in a solution that is 0.249 M in nitrous acid.The acid dissociation constant of nitrous acid is 4.50 × 10-4.


A) 1.12 × 10-4
B) 0.0450
C) 4.25
D) 0.342
E) 5.53

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A 25.0-mL sample of 0.150 M hydrazoic acid is titrated with a 0.150 M NaOH solution.What is the pH after 13.3 mL of base is added? The Ka of hydrazoic acid is 1.9 × 10-5.


A) 4.45
B) 1.34
C) 3.03
D) 4.78
E) 4.66

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