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An ice cube melts and cools the surrounding beverage.(The ice cube is the system. ) Which of the following statement is correct?


A) The system loses heat to the surroundings.
B) The system gains heat from the surroundings.
C) The system does work on the surroundings.
D) The surroundings does work on the system.

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Which of the following processes is endothermic?


A) the freezing of water
B) the combustion of propane
C) a hot cup of coffee (system) cooling on a countertop
D) the chemical reaction in a "hot pack" often used to treat sore muscles
E) the vaporization of rubbing alcohol

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The specific heat capacity of liquid water is 4.18 J/g ∙ K.How many joules of heat are needed to raise the temperature of 5.00 g of water from 25.1°C to 65.3°C?


A) 48.1 J
B) 840 J
C) 1.89 × The specific heat capacity of liquid water is 4.18 J/g ∙ K.How many joules of heat are needed to raise the temperature of 5.00 g of water from 25.1°C to 65.3°C? A) 48.1 J B) 840 J C) 1.89 ×   J D) 2.08 ×   J E) 54.4 J
J
D) 2.08 × The specific heat capacity of liquid water is 4.18 J/g ∙ K.How many joules of heat are needed to raise the temperature of 5.00 g of water from 25.1°C to 65.3°C? A) 48.1 J B) 840 J C) 1.89 ×   J D) 2.08 ×   J E) 54.4 J
J
E) 54.4 J

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According to the following reaction,how much energy is required to decompose 55.0 kg of Fe3O4? The molar mass of Fe3O4 is 231.55 g/mol. Fe3O4(s) → 3 Fe(s) + 2 O2(g) ΔH°rxn = +1118 kJ


A) 1.10 × 106 kJ
B) 2.38 × 102 kJ
C) 2.66 × 105 kJ
D) 1.12 × 103 kJ
E) 3.44 × 104 kJ

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Choose the thermochemical equation that illustrates ΔH°f for Li2SO4.


A) 2 Li+(aq) + SO42-(aq) → Li2SO4(aq)
B) 2 Li(s) + 1/8 S8(s,rhombic) + 2 O2(g) → Li2SO4(s)
C) Li2SO4(aq) → 2 Li+(aq) + SO42-(aq)
D) 8 Li2SO4(s) → 16 Li(s) + S8(s,rhombic) + 16 O2(g)
E) 16 Li(s) + S8(s,rhombic) + 16 O2(g) → 8 Li2SO4(s)

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A piece of iron (mass = 25.0 g) at 398 K is placed in a styrofoam coffee cup containing 25.0 mL of water at 298 K.Assuming that no heat is lost to the cup or the surroundings,what will the final temperature of the water be? The specific heat capacity of iron = 0.449 J/g°C and water = 4.18 J/g°C.


A) 348 K
B) 308 K
C) 287 K
D) 325 K
E) 388 K

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Where does the energy absorbed during an endothermic reaction go?

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During an endothermic reaction,the produ...

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The combustion of titanium with oxygen produces titanium dioxide: Ti(s) + O2(g) → TiO2(s) When 2.060 g of titanium is combusted in a bomb calorimeter,the temperature of the calorimeter increases from 25.00°C to 91.60°C.In a separate experiment,the heat capacity of the calorimeter is measured to be 9.84 kJ/K.The heat of reaction for the combustion of a mole of Ti in this calorimeter is ________ kJ/mol.


A) 14.3
B) 19.6
C) -311
D) -0.154
E) -1.52 × 104

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According to the following reaction,how much energy is evolved during the reaction of 2.50 L B2H6 and 5.65 L Cl2 (Both gases are initially at STP) ? The molar mass of B2H6 is 27.67 g/mol. B2H6(g) + 6 Cl2(g) → 2 BCl3(g) + 6 HCl(g) ΔH°rxn = -1396 kJ


A) 58.7 kJ
B) 156 kJ
C) 215 kJ
D) 352 kJ
E) 508 kJ

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The enthalpy of combustion of gasoline (C8H18) is 5471 kJ mol-1. How much heat will be produced by burning 1 gallon of gasoline at 25°C? (Density of gasoline = 0.703 g/mL;1gallon = 3.78 L)


A) 1.3 × 105 kJ
B) 5451 kJ
C) 2.0 × 104 kJ
D) 2.0 × 104 J

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In the following reaction,energy is given off.Where does the energy go? C(s) +O2 (g) = CO2(g)


A) to the reactants
B) to the products
C) to the system
D) to the surroundings

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Match the following. --w


A) work done by the system on the surroundings
B) system gains thermal energy from surroundings
C) energy flows out of system into the surroundings
D) system loses thermal energy to surroundings
E) work done on the system by the surroundings
F) energy flows into the system from the surroundings

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Which of the following signs on q and w represent a system that is doing work on the surroundings,as well as gaining heat from the surroundings?


A) q = +,w = -
B) q = -,w = +
C) q = +,w = +
D) q = -,w = -
E) None of these represent the system referenced above.

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A motor does 30 kJ of work and loses 4 kJ as heat to the surroundings.What is the change in the internal energy of the motor?


A) -34 kJ
B) +34 kJ
C) -26 kJ
D) +26 kJ

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According to the following thermochemical equation,what mass of H2O (in g) must form in order to produce 488 kJ of energy? SiO2(s) + 4 HF(g) → SiF4(g) + 2 H2O(l) ΔH°rxn = -184 kJ


A) 34.0 g
B) 51 g
C) 27.1 g
D) 95.4 g
E) 47.8 g

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Which of the following (with specific heat capacity provided) would show the smallest temperature change upon gaining 200.0 J of heat?


A) 50.0 g Al,CAl = 0.903 J/g°C
B) 50.0 g Cu,CCu = 0.385 J/g°C
C) 25.0 g granite,Cgranite = 0.79 J/g°C
D) 25.0 g Au,CAu = 0.128 J/g°C
E) 25.0 g Ag,CAg = 0.235 J/g°C

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Calculate the amount of heat (in kJ) necessary to raise the temperature of 47.8 g benzene by 57.0 K.The specific heat capacity of benzene is 1.05 J/g°C


A) 1.61 kJ
B) 16.6 kJ
C) 2.59 kJ
D) 2.86 kJ
E) 3.85 kJ

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Calculate the work done by the system when 2 moles of hydrogen gas is produced by the following reaction in a flask fitted with an inflatable balloon. Zn(s) +2HCl(aq) = ZnCl2(aq) + H2(g)


A) +4.8 kJ
B) -4.8 kJ
C) 0 kJ
D) 2.0kJ

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When 1.50 mol of CH4(g) reacts with excess Cl2(g) at constant pressure according to the chemical equation shown below,1062 kJ of heat are released.Calculate the value of ΔH for this reaction,as written. 2 CH4(g) + 3 Cl2(g) → 2 CHCl3(l) + 3 H2(g) ΔH = ?


A) -1420 kJ
B) -708 kJ
C) +708 kJ
D) +1420 kJ

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Use the ΔH°f information provided to calculate ΔH°rxn for the following: ΔH°f (kJ/mol) SO2Cl2(g) + 2 H2O(l) → 2 HCl(g) + H2SO4(l) ΔH°rxn = ? SO2Cl2(g) -364 H2O(l) -286 HCl(g) -92 H2SO4(l) -814


A) -256 kJ
B) +161 kJ
C) -62 kJ
D) +800.kJ
E) -422 kJ

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