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It takes 18.2 kJ of energy to raise the temperature of 55.2g of an unknown liquid from 30.0°C to 47.0°C.What is the specific heat of the unknown liquid


A) 1. 17 J/(g ∙ °C)
B) 205J/(g ∙ °C)
C) 89.0 J/(g ∙ °C)
D) 19.4 J/(g ∙ °C)

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D

Energy that is associated with the relative positions of electrons and nuclei in atoms and molecules is called


A) kinetic energy.
B) thermal energy.
C) gravitational energy.
D) chemical energy.

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Use the standard reaction enthalpies given below to determine ΔH°rxn for the following reaction 2 NO(g) + O2(g) → 2 NO2(g) ΔH°rxn = ? Given: N2(g) + O2(g) → 2 NO(g) ΔH°rxn = +183 kJ 1/2 N2(g) + O2(g) → NO2(g) ΔH°rxn = +33 kJ


A) -150. kJ
B) -117 kJ
C) -333 kJ
D) +115 kJ
E) +238 kJ

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Which one of the following elements is NOT in its standard state?


A) Br2(g)
B) F2(g)
C) Hg(l)
D) Na(s)
E) Cl2(g)

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Which of the following processes are endothermic?


A) the reaction associated with the lattice energy of LiCl
B) the reaction associated with the ionization energy of potassium
C) the reaction associated with the heat of formation of CaS
D) the formation of F2 from its elements in their standard states
E) None of the above are endothermic.

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Determine the specific heat capacity of an alloy that requires 59.3 kJ to raise the temperature of 150.0 g alloy from 298 K to 398 K.


A) 4.38 J/g°C
B) 2.29 J/g°C
C) 3.95 J/g°C
D) 2.53 J/g°C
E) 1.87 J/g°C

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If a block of gold requires 1.42 kJ of energy to raise the temperature from 120.0°C to 240.0°C,what is the mass of the block? The specific heat capacity of gold is 0.129 J/g-K.


A) 92.0 g
B) 35.3 g
C) 186 g
D) 55.7 g

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Use the bond energies provided to estimate ΔH°rxn for the reaction below. CH3OH(l) + 2 O2(g) → CO2(g) + 2 H2O(g) ΔH°rxn = ? Bond Bond Energy (kJ/mol) C-H 414 C-O 360 C=O 799 O=O 498 O-H 464


A) +473 kJ
B) -91 kJ
C) -486 kJ
D) -392 kJ
E) +206 kJ

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Give the units of heat capacity.


A) J/°C
B) J/g °C
C) Jmole/°C
D) g/°C
E) mole/°C

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Choose the reaction that illustrates ΔH°f for Mg(NO3) 2.


A) Mg(s) + N2(g) + 3O2(g) → Mg(NO3) 2(s)
B) Mg2+(aq) + 2 NO3-(aq) → Mg(NO3) 2(aq)
C) Mg(s) + 2 N(g) + 6 O(g) → Mg(NO3) 2(s)
D) Mg(NO3) 2(aq) → Mg2+(aq) + 2 NO3-(aq)
E) Mg(NO3) 2(s) → Mg(s) + N2(g) + 3O2(g)

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Where does the energy absorbed during an endothermic reaction go?

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During an endothermic reaction,the produ...

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When 10.00 moles of H2(g) reacts with 5.000 mol of O2(g) to form 10.00 mol of H2O(l) at 25°C and a constant pressure of 1.00 atm.If 683.0 kJ of heat are released during this reaction,and PΔV is equal to -37.00 kJ,then


A) ΔH° = +683.0 kJ and ΔE° = +720.0 kJ.
B) ΔH° = +683.0 kJ and ΔE° = +646.0 kJ.
C) ΔH° = -683.0 kJ and ΔE° = -646.0 kJ.
D) ΔH° = -683.0 kJ and ΔE° = -720.0 kJ.

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According to the following thermochemical equation,what mass of HF (in g) must react in order to produce 345 kJ of energy? Assume excess SiO2. SiO2(s) + 4 HF(g) → SiF4(g) + 2 H2O(l) ΔH°rxn = -184 kJ


A) 42.7 g
B) 37.5 g
C) 150. g
D) 107 g
E) 173 g

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Which of the following statements is TRUE?


A) State functions do not depend on the path taken to arrive at a particular state.
B) DErxn can be determined using constant volume calorimetry.
C) Energy is neither created nor destroyed, excluding nuclear reactions.
D) ΔHrxn can be determined using constant pressure calorimetry.
E) All of the above are true.

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E

At 1 atm pressure,the heat of sublimation of gallium is 277.0kJ/mol and the heat of vaporization is 271.0 kJ/mol.To the correct number of significant figures,how much heat is required to melt 5.50 mol of gallium at 1 atm pressure?


A) 6 kJ
B) 33 kJ
C) 244 kJ
D) 274 kJ

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B

The combustion of titanium with oxygen produces titanium dioxide: Ti(s) + The combustion of titanium with oxygen produces titanium dioxide: Ti(s) +   (g) →   (s)  When 2.060 g of titanium is combusted in a bomb calorimeter,the temperature of the calorimeter increases from 25.00°C to 91.60°C.In a separate experiment,the heat capacity of the calorimeter is measured to be 9.84 kJ/K.The heat of reaction for the combustion of a mole of Ti in this calorimeter is ________ kJ/mol. A)  14.3 B)  19.6 C)  -311 D)  -0.154 E)  -1.52 ×  (g) → The combustion of titanium with oxygen produces titanium dioxide: Ti(s) +   (g) →   (s)  When 2.060 g of titanium is combusted in a bomb calorimeter,the temperature of the calorimeter increases from 25.00°C to 91.60°C.In a separate experiment,the heat capacity of the calorimeter is measured to be 9.84 kJ/K.The heat of reaction for the combustion of a mole of Ti in this calorimeter is ________ kJ/mol. A)  14.3 B)  19.6 C)  -311 D)  -0.154 E)  -1.52 ×  (s) When 2.060 g of titanium is combusted in a bomb calorimeter,the temperature of the calorimeter increases from 25.00°C to 91.60°C.In a separate experiment,the heat capacity of the calorimeter is measured to be 9.84 kJ/K.The heat of reaction for the combustion of a mole of Ti in this calorimeter is ________ kJ/mol.


A) 14.3
B) 19.6
C) -311
D) -0.154
E) -1.52 × The combustion of titanium with oxygen produces titanium dioxide: Ti(s) +   (g) →   (s)  When 2.060 g of titanium is combusted in a bomb calorimeter,the temperature of the calorimeter increases from 25.00°C to 91.60°C.In a separate experiment,the heat capacity of the calorimeter is measured to be 9.84 kJ/K.The heat of reaction for the combustion of a mole of Ti in this calorimeter is ________ kJ/mol. A)  14.3 B)  19.6 C)  -311 D)  -0.154 E)  -1.52 ×

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Use the ΔH°f and ΔH°rxn information provided to calculate ΔH°f for SO3(g) ΔH°f (kJ/mol) 2 SO2(g) + O2(g) → 2 SO3(g) ΔH°rxn = -198 kJ SO2(g) -297


A) -792 kJ/mol
B) -248 kJ/mol
C) -495 kJ/mol
D) -578 kJ/mol
E) -396 kJ/mol

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Which of the following processes is endothermic?


A) the freezing of water
B) the combustion of butane
C) a hot cup of coffee (system) cools on a countertop
D) the chemical reaction in a "hot pack" often used to treat sore muscles
E) the vaporization of rubbing alcohol

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Use the ΔH°f and ΔH°rxn information provided to calculate ΔH°f for IF ΔH°f (kJ/mol) IF7(g) + I2(g) → IF5(g) + 2 IF(g) ΔH°rxn = -89 kJ IF7(g) 941 IF5(g) 840


A) 101 kJ/mol
B) -146 kJ/mol
C) -190. kJ/mol
D) -95 kJ/mol
E) 24 kJ/mol

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What is the enthalpy change (in kJ) of a chemical reaction that raises the temperature of 250.0 mL of solution having a density of 1.25 g/ml by 7.80°C? (The specific heat of the solution is 3.74 J/g∙K.)


A) -7.43 kJ
B) -12.51 kJ
C) 8.20 kJ
D) -9.12 kJ
E) 6.51 kJ

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