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Which of the following substances is most likely to be a gas at room temperature and atmospheric pressure?


A) Cs
B) SO2
C) I2
D) CCl4
E) Ni

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Select the pair of substances which has the one with the higher equilibrium vapor pressure at a given temperature listed first.


A) H2O, H2S
B) CH3CH2OH, CH3OH
C) CH3COCH3, CH3CH2CH2OH
D) NH3, PH3
E) Br2, Cl2

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Identify the type of solid shown in the image. Identify the type of solid shown in the image.   A) metallic B) ionic C) network D) nonpolar molecular E) polar molecular


A) metallic
B) ionic
C) network
D) nonpolar molecular
E) polar molecular

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Which of the following is not an attractive force that acts between the individual molecules of CH3OH?


A) London dispersion forces
B) dipole-dipole forces
C) hydrogen-bonding forces
D) covalent bonds
E) none of these is correct

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The pictured change of state occurs at constant temperature even though heat is being added.Where does this change of state occur on the cooling curve? The pictured change of state occurs at constant temperature even though heat is being added.Where does this change of state occur on the cooling curve?   A) AB B) BC C) CD D) DE E) EF


A) AB
B) BC
C) CD
D) DE
E) EF

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Rank the following substances in order of increasing intermolecular forces: Ar, H2O, N2, O2


A) Ar < H2O < N2 < O2
B) Ar < H2O < O2 < N2
C) H2O < N2 < O2 < Ar
D) N2 < O2 < Ar < H2O
E) Ar < N2 < O2 < H2O

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The physical properties of a substance influenced by the strength of intermolecular forces include all of the following except:


A) melting point.
B) boiling point.
C) viscosity.
D) vapor pressure.
E) mass.

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Which substance has the highest melting point?


A) Cu
B) C6H14
C) Rn
D) C (graphite)
E) I2

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Network covalent substances have the highest melting points of all substances.

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Which of the following statements regarding intermolecular forces is incorrect?


A) An intermolecular force is an attractive force that operates between molecules.
B) Bonding forces are much stronger than intermolecular forces.
C) London dispersion forces occur in all atoms and molecules.
D) London dispersion forces are the result of permanent dipoles in atoms or molecules.
E) Molecules which have hydrogen bonded to F, O, or N can undergo hydrogen-bonding.

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The atmospheric pressure on Mount Everest is about 0.30 atm.From the vapor pressure curve of propane, it can be seen the boiling point of propane at this elevation is about _________. The atmospheric pressure on Mount Everest is about 0.30 atm.From the vapor pressure curve of propane, it can be seen the boiling point of propane at this elevation is about _________.   A) -137<sup>o</sup>C B) -120<sup>o</sup>C C) -67<sup>o</sup>C D) -42<sup>o</sup>C E) 0<sup>o</sup>C


A) -137oC
B) -120oC
C) -67oC
D) -42oC
E) 0oC

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Which of the following statements is correct?


A) The phase change from solid to liquid is exothermic.
B) Liquids boil at lower than normal temperatures in Death Valley, since it is below sea level.
C) A substance with a low boiling point would be expected to have a relatively low vapor pressure at a low temperature.
D) The phase change from liquid to gas is exothermic.
E) When a substance condenses, heat energy is given off.

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From the vapor pressure curve of acetone, it can be seen that the normal boiling point of acetone is about _________. From the vapor pressure curve of acetone, it can be seen that the normal boiling point of acetone is about _________.   A) -50<sup>o</sup>C B) 0<sup>o</sup>C C) 50<sup>o</sup>C D) 57<sup>o</sup>C E) 100<sup>o</sup>C


A) -50oC
B) 0oC
C) 50oC
D) 57oC
E) 100oC

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Identify the type of solid shown in the image. Identify the type of solid shown in the image.   A) metallic B) ionic C) network D) nonpolar molecular E) polar molecular


A) metallic
B) ionic
C) network
D) nonpolar molecular
E) polar molecular

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Which of the following molecules experience dipole-dipole forces?


A) CO2
B) SO2
C) CCl4
D) H2S
E) both SO2 and H2S

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Consider the melting point of the following solids.Which of these solids is most likely a network solid?


A) SiF4, -90oC
B) CO2, -57oC
C) BN, 3000oC
D) KBr, 734oC
E) GeBr4, 26oC

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Calculate the amount of heat energy required to convert 35.0 g of ice at -12.5 °\degree C to water at 24.0 °\degree C.(Cwater = 4.18 J/g °\degree C; Cice = 2.03 J/g °\degree C; molar heat of fusion of ice = 6.01 x 103 J/mol)


A) 8.88 x 102 J
B) 1.17 x 104 J
C) 1.61 x 1010 J
D) 3.51 x 103 J
E) 1.61 x 104 J

Correct Answer

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Which of the following statements regarding the liquid state is incorrect?


A) Liquids are about 1000 times denser than gases.
B) Liquids are normally about 90-95% as dense as their corresponding solid.
C) The viscosity of a liquid is a measure of its resistance to flow.
D) Molecules with high intermolecular forces will have high surface tension.
E) Surface tension increases as temperature increases.

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What phase transition is occurring between points B and C on the heating curve? What phase transition is occurring between points B and C on the heating curve?   A) melting B) condensation C) evaporation D) sublimation E) deposition


A) melting
B) condensation
C) evaporation
D) sublimation
E) deposition

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Which of the following has the highest boiling point?


A) H2
B) HF
C) HCl
D) HBr
E) HI

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