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Which of the following indicators would be the best to use when 0.050 M benzoic acid (Ka = 6.6*10¯5) is titrated with 0.05 M NaOH?


A) bromphenol blue, pH range: 3.0 to 4.5
B) bromcresol green, pH range: 3.8 to 5.4
C) alizarin, pH range: 5.7 to 7.2
D) phenol red, pH range: 6.9 to 8.2
E) phenolphthalein, pH range: 8.0 to 10.1

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The solubility of calcium chromate is 1.56 *10¯3 g/100 mL of solution. What is the Ksp for CaCrO4?


A) 2.4 * 10¯4
B) 1.5 *10¯5
C) 7.6 * 10¯6
D) 1.0 * 10¯8
E) < 1.0 * 10¯8

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A solution is prepared by dissolving 20.0 g of K2HPO4 and 25.0 g of KH2PO4 in enough water to produce 1.0 L of solution. What is the pH of this buffer? For phosphoric acid (H3PO4) , Ka2 = 6.2 *10¯8


A) 7.70
B) 7.42
C) 7.21
D) 7.00
E) 6.72

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Write the ion product expression for magnesium fluoride, MgF2.


A) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
B) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
C) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
D) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)
E) Write the ion product expression for magnesium fluoride, MgF<sub>2</sub>. A)    B)    C)    D)    E)

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A formic acid buffer containing 0.50 M HCOOH and 0.50 M HCOONa has a pH of 3.77. What will the pH be after 0.010 mol of NaOH has been added to 100.0 mL of the buffer?


A) 3.67
B) 3.78
C) 3.81
D) 3.85
E) 3.95

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A buffer is to be prepared by adding solid sodium acetate to 0.10 M CH3COOH. Which of the following concentrations of sodium acetate will produce the most effective buffer?


A) 3.0 M CH3COONa
B) 2.5 M CH3COONa
C) 2.0 M CH3COONa
D) 1.5 M CH3COONa
E) 0.30 M CH3COONa

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A change in pH will significantly affect the solubility of which, if any, of the following compounds?


A) BaF2
B) CuCl
C) CuBr
D) AgI
E) None of the solubilities will be significantly affected.

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Buffer solutions with the component concentrations shown below were prepared. Which of them should have the lowest pH?


A) [CH3COOH] = 0.25 M, [CH3COO¯] = 0.25 M
B) [CH3COOH] = 0.75 M, [CH3COO¯] = 0.75 M
C) [CH3COOH] = 0.75 M, [CH3COO¯] = 0.25 M
D) [CH3COOH] = 0.25 M, [CH3COO¯] = 0.75 M
E) [CH3COOH] = 1.00 M, [CH3COO¯] = 1.00 M

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What is the [H3O+] in a solution that consists of 1.5 M NH3 and 2.5 NH4Cl? Kb = 1.8 * 10¯5


A) 1.1 * 10¯5 M
B) 3.0 * 10¯6 M
C) 3.3 * 10¯9 M
D) 9.3 * 10¯10 M
E) None of these choices is correct.

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The salts X(NO3) 2 and Y(NO3) 2 (where X+ and Y+ are metal ions) are dissolved in water to give a solution which is 0.1 M in each of them. Using the Ksp values listed below, decide which aqueous reagent, if any, will definitely precipitate X+ before precipitating Y+ from solution. Given Ksp values: XCl2, 1 * 10¯5; YCl2, 1 * 10¯10; X(OH) 2, 1 *10¯10; Y(OH) 2, 1 * 10¯5


A) 1 M NaNO3
B) 1 M HCl
C) 1 M HNO3
D) 1 M NaCl
E) None of these reagents will accomplish the precipitation.

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When 0.300 g of a diprotic acid was titrated with 0.100 M LiOH, 40.0 mL of the LiOH solution was needed to reach the second equivalence point. Identify the formula of the diprotic acid.


A) H2S
B) H2C2O4
C) H2C4H4O6
D) H2Se
E) H2Te

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The equivalence point in a titration is defined as the point when the indicator changes color.

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Calculate the solubility of strontium fluoride, SrF2, in pure water. Ksp = 2.6 * 10¯9


A) 1.4 * 10¯3 M
B) 3.4 * 10¯4 M
C) 8.7 * 10¯4 M
D) 5.l *10¯5 M
E) < 1.0 * 10¯5 M

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You need to use KH2PO4 and K2HPO4 to prepare a buffer with a pH of 7.45. Which of the following ratios of [base]/[acid] is required? For phosphoric acid, (H3PO4) , Ka2 = 6.2 *10¯8


A) [base]/[acid] = 1.75
B) [base]/[acid] = 1.27
C) [base]/[acid] = 1.24
D) [base]/[acid] = 0.79
E) [base]/[acid] = 0.57

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What is the pH of a buffer that consists of 0.45 M CH3COOH and 0.35 M CH3COONa? Ka = 1.8 *10¯5


A) 4.49
B) 4.64
C) 4.85
D) 5.00
E) 5.52

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