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What type of reaction mechanism accounts for the reaction of an alkene with HBr to give an alkyl bromide?


A) nucleophilic addition
B) electrophilic addition
C) radical addition
D) elimination

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What type of reactive intermediate is formed in the reaction of an alkene with Br2 and water to give a bromohydrin?


A) carbocation
B) carbanion
C) radical
D) cyclic bromonium ion

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What is the best choice of reagent to perform the following transformation? What is the best choice of reagent to perform the following transformation?   A)  Br<sub>2</sub> B)  HBr C)  Br<sub>2</sub>, H<sub>2</sub>O D)  N-bromosuccinimide


A) Br2
B) HBr
C) Br2, H2O
D) N-bromosuccinimide

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What type of reactive intermediate is formed in the reaction of an alkene with aqueous acid to give an alcohol?


A) carbocation
B) carbanion
C) radical
D) carbene

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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What is (are) the major organic product(s) obtained from the following reaction? What is (are)  the major organic product(s)  obtained from the following reaction?     A)  only 1 B)  only 2 C)  only 3 D)  only 1 and 2 What is (are)  the major organic product(s)  obtained from the following reaction?     A)  only 1 B)  only 2 C)  only 3 D)  only 1 and 2


A) only 1
B) only 2
C) only 3
D) only 1 and 2

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What is the best choice of reagent(s) to perform the following transformation? What is the best choice of reagent(s)  to perform the following transformation?   A)  H<sub>2</sub>O, H<sub>2</sub>SO<sub>4</sub> B)  HgSO<sub>4</sub>; followed by NaBH<sub>4</sub> C)  BH<sub>3</sub>; followed by H<sub>2</sub>O<sub>2</sub> D)  OsO<sub>4</sub>; followed by NaHSO<sub>3</sub>


A) H2O, H2SO4
B) HgSO4; followed by NaBH4
C) BH3; followed by H2O2
D) OsO4; followed by NaHSO3

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Which of the following reactions of alkenes is not stereospecific?


A) bromination (treatment with Br2 in CHCl3)
B) hydrogenation (treatment with H2/Pt)
C) acid-catalyzed hydration (treatment with aqueous H2SO4)
D) bromohydrin formation (treatment with Br2/H2O)

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Provide a neatly drawn mechanism for the following reaction, including curved arrows to show the movement of paris of electrons and the structure of reactive intermediates.

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blured image The reaction proceeds in thre...

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

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Which of the following reactions of alkenes takes place with anti stereospecificity?


A) bishydroxylation (treatment with OsO4 followed by NaHSO3)
B) hydrogenation (treatment with H2/Pt)
C) addition of HBr (treatment with HBr)
D) bromohydrin formation (treatment with Br2, H2O)

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What type of carbocation is shown? What type of carbocation is shown?   A)  primary B)  secondary C)  tertiary D)  quaternary


A) primary
B) secondary
C) tertiary
D) quaternary

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What is the correct order of stability of the following carbocations (more stable > less stable) ? What is the correct order of stability of the following carbocations (more stable > less stable) ?   A)  1 > 2 > 3 B)  2 > 1 > 3 C)  2 > 3 > 1 D)  3 > 2 > 1


A) 1 > 2 > 3
B) 2 > 1 > 3
C) 2 > 3 > 1
D) 3 > 2 > 1

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Provide the structure of the key intermediate in the following reaction? Provide the structure of the key intermediate in the following reaction?

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?   A)  1 B)  2 C)  3 D)  4


A) 1
B) 2
C) 3
D) 4

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What is the major organic product obtained from the following reaction? What is the major organic product obtained from the following reaction?

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What is the best choice of reagent(s) to perform the following transformation? What is the best choice of reagent(s) to perform the following transformation?

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(i) OsO4; (...

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What is (are) the major organic product(s) obtained from the following reaction? What is (are)  the major organic product(s)  obtained from the following reaction?     A)  only 1 B)  only 2 C)  only 3 D)  only 1 and 2 What is (are)  the major organic product(s)  obtained from the following reaction?     A)  only 1 B)  only 2 C)  only 3 D)  only 1 and 2


A) only 1
B) only 2
C) only 3
D) only 1 and 2

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