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A buffer solution contains acetic acid (HC2H3O2) at a concentration of 0.225 M and sodium acetate (NaC2H3O2) at a concentration of 0.164 M.The value of Ka for acetic acid is 1.75 × 10−5.What is the pH of this buffer solution?


A) 0.137
B) 0.862
C) 2.40
D) 4.62
E) 4.76

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Consider two beakers,one containing 1.0 M HCl and the other containing 1.0 M CH3COOH.Which solution would have the lowest pH?


A) 1.0 M CH3COOH because its solution contains a lower hydronium ion concentration than 1.0 M HCl
B) 1.0 M HCl because its solution contains a higher hydronium ion concentration than 1.0 M CH3COOH
C) 1.0 M HCl because its solution contains a lower hydronium ion concentration than 1.0 M CH3COOH
D) 1.0 M CH3COOH because its solution contains a higher hydronium ion concentration than 1.0 M HCl
E) Both solutions would have the same pH because they have the same concentration.

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A buffer solution is prepared by placing twice the concentration of propanoic acid (C2H5COOH,Ka=1.34 ×10−5) as the concentration of its conjugate base sodium propanoate into a flask.The pH of the resulting buffer solution is best described as which of the following?


A) less than 4.87
B) 4.87
C) between 4.87 and 9.00
D) greater than 11.00
E) Undeterminable; the concentrations of the acid and conjugate base must be given.

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All buffer solutions operate at a pH at or near 7.

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Formic acid (HCO2H) is a weak acid found in the venom of bees and ant stings.Which of the following is an accurate statement concerning an aqueous solution of formic acid? HCO2H(aq) + H2O(l) ? H3O+(aq) + HCO2?(aq) Ka = 1.8 × 10?4


A) The reaction between formic acid and water is slow,due to the low value for Ka.
B) A formic acid solution predominantly contains undissociated HCO2H molecules.
C) A formic acid solution predominantly contains H3O+ and HCO2? ions.
D) A formic acid solution contains a greater concentration of dissolved ions than it does neutral formic acid molecules.
E) A formic acid solution contains equal amounts of H3O+ and HCO2H.

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Choose the best classification of the reaction represented by the following equation: C6H12O6(s) + 6O2(g) → 6CO2(g) + 6H2O(l)


A) combustion
B) acid-base
C) precipitation
D) decomposition
E) combination

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Which of the following correctly describes what is meant by the term neutralization?


A) the reaction between hydroxide (OH) and water to form a base
B) the reaction between a proton (H+) and water to form a hydronium ion (H3O+)
C) the reaction between an acid and a base to form a salt and water
D) the reaction between two molecules of water,one acting as an acid and the other acting as a base
E) the reaction between an oxidizing agent and a reducing agent

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A patient's urine sample gave a reading of pH = 8.2.What is the value of [H3O+] in this solution?


A) 6.0 × 10-9 M
B) 0.91 M
C) 1.6 × 10-8 M
D) 1.6 × 108 M
E) 2.7 × 10-4 M

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Titration of 25.0 mL of an HCl solution of unknown concentration requires 14.8 mL of 0.100 M NaOH.What is the molar concentration of the HCl solution? NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)


A) 0.592 M
B) 5.87 M
C) 0.0592 M
D) 0.0692 M
E) 1.25 M

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For the reaction shown below,which of the following is a conjugate acid-base pair? C5H5N(aq) + H2O(l) ? C5H5NH+(aq) + OH?(aq)


A) C5H5N,H2O
B) C5H5N,C5H5NH+
C) C5H5NH+,OH?
D) H2O,OH?
E) C5H5N,C5H5NH+ and H2O,OH?

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The pH of a 12.0 M solution of HCl is 1.1.

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If the hydronium ion concentration of an aqueous solution at 25°C is 5 × 10−6 M,what is the hydroxide ion concentration?


A) 2 × 10−10 M
B) 2 × 10−9 M
C) 2 × 10−8 M
D) 2 × 107 M
E) 2 × 1019 M

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What is the hydronium ion concentration of a solution with a pH of 6.0?


A) 1 × 106 M
B) 1 × 10−6 M
C) 6 × 101 M
D) 6 × 10−1 M
E) 6 × 10−14 M

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Consider the following generalized buffer solution equilibrium: BH+(aq) + H2O(l) ? H3O+(aq) + B(aq) When a small amount of a strong base such as sodium hydroxide is added to the solution,which of the four species shown would experience an increase in concentration? (Hint: Use LeChatelier's principle.)


A) BH+
B) H2O
C) H3O+
D) B
E) None of the species would increase in concentration.

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A standard solution is a solution whose concentration is accurately known.

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What is the [OH] of a solution that has a pH = 10.95?


A) 1.03 M
B) 1.1 × 10-11 M
C) 8.9 × 10-4 M
D) 3.05 M
E) 7.4 × 10-5 M

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Which statement concerning the relative strength of acids is FALSE?


A) Strong and weak acids differ in their extent of proton transfer to water.
B) Strong acids are good proton donors; weak acids are poor proton donors.
C) A strong acid completely transfers its protons to water; a weak acid only partially transfers its protons to water.
D) Strong acids produce strong conjugate bases; weak acids produce weak conjugate bases.
E) A strong acid produces more hydronium ions in water than a weak acid of the same concentration.

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What is always a characteristic of a solution that contains a buffer?


A) The solution is neutral and has a pH of 7.
B) The solution contains a small amount of solute dissolved in a large volume of solvent.
C) The solution has been diluted by the addition of solvent.
D) The solution resists large changes in pH when small amounts of acids or bases are added.
E) The solution maintains a constant pH value; no amount of added acid or base can change the pH.

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Which of the following best represents the autoionization,or self-ionization,of water?


A) H2O(l) ? H+(aq) + OH-(aq)
B) 2H2O(l) ? 2H2(aq) + O2(aq)
C) 2H2O(l) ? H3O+(aq) + OH-(aq)
D) H2O(l) ? H2(aq) + O2-(aq)
E) H+(aq) + OH-(aq) ? H2O(l)

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A solution containing a buffer has an initial pH of 8.78.If a student adds 5 drops of NaOH(aq) to this solution,what would be a reasonable pH for the resulting solution?


A) 7.00
B) 8.64
C) 8.78
D) 8.89
E) 12.25

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